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Although the reaction of PhSeBr and 1a generating the SeN intermediate INT1-Se is endothermic by 12.6 kcal mol 1 , INT1-Se may readily undergo a Se-centred [2,3]-sigmatropic rearrangement to generate an ortho -Se = N substituted dearomatized species ( INT2-Se ) via TS1-Se , with a barrier of 12.7 kcal mol 1

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miR-99a/b has been associated with tumor pathogenesis and development of several types of human cancers such as renal cell carcinoma (Li et al., 2011), and NSCLC (Wang et al

Therefore, further research confirmed that CHE is a functional inhibitor of Bcl-xL, bound at the BH region of Bcl-xL (Zhang et al., 2006), and was reported to interfere specifically with the interaction between Bcl-xL and Bax, which act directly on the mitochondria from tumor cells and lead to the release of Cyt-c