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A randomized, placebo-controlled study in 52 subjects (mean age, 30 years) with relapsing-remitting multiple sclerosis found an increase in total antioxidant capacity in blood with lipoic acid supplementation (1,200 mg/day for 12 weeks) yet not in the activity of specific antioxidant enzymes (superoxide dismutase and glutathione peroxidase) (97)

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DOI: Published: Publisher Name: Springer, Cham Print ISBN: 978-3-031-36158-6 Online ISBN: 978-3-031-36159-3 eBook Packages: Biomedical and Life SciencesBiomedical and Life Sciences (R0)

doi:10.1007/s10029-012-0988-0

Removal of the second-sphere influence of the on-face hydrogen bond between the hydroxyl groups T13 as in the T13V and T13A mutants elevates the pKa of enzyme-bound GSH by about 0.7 pKa units