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This inhibitory effect observed in both experimental conditions may be due to the fact that glutathione reacts with the orthodiquinones produced by the enzymatic oxidation of hydroxycinnamic acids to form the grape reaction product (GRP) [23, 31, 55, 56]

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At the molecular level, the stress and strain on the ACL fibers due to impingement can lead to microstructural changes within the collagen matrix

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, without pretreatment) by MALDI-MS for faster turnaround or indirectly via pretreatment steps designed to concentrate analytes and reduce interference from biological matrices