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Sample and instrument details are given with the spectrum Set 1 Sample: Conditions: Spectrometer: 1: 1D 1H Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 2: 2D [1H,1H]-TOCSY Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 3: 1D DEPT90 Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 4: 1D DEPT135 Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 5: 2D [1H,13C]-HSQC Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 6: 2D [1H,13C]-HMBC Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 7: 2D [1H,1H]-COSY Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz 8: 2D [1H,13C]-HMQC Sample: 100mM in D2O, ref: DSS Conditions: temperature: 298K, pH: 7.4 Spectrometer: Bruker DMX - 600MHz

1) from 3,4- cis -leucoanthocyanidins ( 2 ) to anthocyanidins ( 3 ) is thought to be catalysed by the Fe/-ketoglutarate-dependent dioxygenase leucoanthocyanidin dioxygenase (LDOX), also called anthocyanidin synthase (ANS) 8,9

The question is whether the foundation has been correctly read yet

Animal and in vitro evidence Zinc deficiency has been shown to increase endothelial cell apoptosis and amplify the detrimental effects of oxidized LDL in atherosclerosis 47